The brown crust on a seared surface comes from the Maillard reaction, a set of non-enzymatic reactions between amino acids and sugars that happens when food is heated. It is the same family of reactions behind toast, roasted coffee and a golden bread crust. It produces the brown colour and a wide range of flavour and aroma compounds (Britannica; American Chemical Society).
These reactions need heat well above the boiling point of water. The Exploratorium notes that they happen above roughly 140°C (280°F), while liquid water cannot get hotter than 100°C (212°F). That is why boiled or steamed food does not brown (Exploratorium).





